Chiral Supramolecular Materials from Columnar Liquid Crystals

TitleChiral Supramolecular Materials from Columnar Liquid Crystals
Publication TypeJournal Article
Year of Publication2004
AuthorsVillazor, KR, Swager, TM
JournalMolecular Crystals and Liquid Crystals
Volume410
Pagination247–253
Date Publishedjan
ISSN1542-1406
Keywordsdiketonate prepn chirality octahedral iron complex crosslinking diene, liq crystal diketonate iron complex order mesophase
Abstract

Several $\beta$-diketonate ligands were synthesized which have a chiral directing element and/or a polymerizable moiety. Octahedral iron complexes of these ligands were crosslinked in the columnar hexagonal phase using acyclic diene metathesis (ADMET) polymn. The resulting liq. crystal materials were chiral and retained the order of the mesophase. [on SciFinder(R)]

URLhttp://www.tandfonline.com/doi/abs/10.1080/15421400490436070
DOI10.1080/15421400490436070