MIT

Conducting Thiophene-Annulated Azepine Polymers

Title

Conducting Thiophene-Annulated Azepine Polymers

Publication Type
Journal Article
Year of Publication
2010
Journal
Macromolecules
Volume
43
Pagination
5233–5237
Date Published
jun
ISSN
0024-9297
Abstract
We report the synthesis of annulated azepines, conjugated seven-membered ring systems with nitrogen, designed to undergo an electrochem. controlled bent-to-planar transformation driven by aromatization. A Pd-catalyzed double amination strategy enabled us to synthesize annulated azepines, which are thermally and electrochem. stable even in highly oxidized states. Several methods of chem. and electrochem. polymn. yielded azepine-based materials that were demonstrated to retain their redox properties in the solid state under ambient conditions. Because of their redox stability and cond., these polymers could find utility in actuating materials research. [on SciFinder(R)]