Title | Main-Chain Calixarene Polymers: Conformational Effects on Polymerization |
Publication Type | Journal Article |
Year of Publication | 2006 |
Authors | Yang, Y, Swager, TM |
Journal | Macromolecules |
Volume | 39 |
Pagination | 2013–2015 |
Date Published | mar |
ISSN | 0024-9297 |
Keywords | main chain calixarene polymer polymn conformational effect |
Abstract | We have synthesized high-mol.-wt. main-chain calixarene homopolymers via linkages on lower rims. We have found that the calixarene conformation has a profound influence on the polymn. Our synthetic methodol. can be applied to the polymns. of other sterically demanding and conformationally flexible monomers. Main-chain calixarene polymers linked through the lower rims present new opportunities to create efficient sepns., and materials for sensing and actuation, as a result of their dynamic receptor properties. [on SciFinder(R)] |
URL | http://pubs.acs.org/doi/abs/10.1021/ma052630x |
DOI | 10.1021/ma052630x |