Synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl radical.

TitleSynthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl radical.
Publication TypeJournal Article
Year of Publication2010
AuthorsDane, EL, Swager, TM
JournalThe Journal of organic chemistry
Volume75
Pagination3533–6
Date Publishedmay
ISSN1520-6904
KeywordsAllyl Compounds, Allyl Compounds: chemical synthesis, Allyl Compounds: chemistry, Crystallography, Free Radicals, Free Radicals: chemical synthesis, Free Radicals: chemistry, Models, Molecular, Molecular Structure, Solubility, Water, Water: chemistry, X-Ray
Abstract

The design and synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl (BDPA) radical via the conjugate addition of a derivatized fluorene nucelophile is described. The compound is designed for use in dynamic nuclear polarization NMR. Its 9 GHz EPR spectrum in glycerol/water is reported.
URLhttp://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=2882179&tool=pmcentrez&rendertype=abstract
DOI10.1021/jo100577g