|Title||Synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl radical.|
|Publication Type||Journal Article|
|Year of Publication||2010|
|Authors||Dane, EL, Swager, TM|
|Journal||The Journal of organic chemistry|
|Keywords||Allyl Compounds, Allyl Compounds: chemical synthesis, Allyl Compounds: chemistry, Crystallography, Free Radicals, Free Radicals: chemical synthesis, Free Radicals: chemistry, Models, Molecular, Molecular Structure, Solubility, Water, Water: chemistry, X-Ray|
The design and synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl (BDPA) radical via the conjugate addition of a derivatized fluorene nucelophile is described. The compound is designed for use in dynamic nuclear polarization NMR. Its 9 GHz EPR spectrum in glycerol/water is reported.