MIT

Synthesis and properties of a novel cross-conjugated conductive polymer precursor: poly(3,4-diisopropylidenecyclobutene).

Title

Synthesis and properties of a novel cross-conjugated conductive polymer precursor: poly(3,4-diisopropylidenecyclobutene).

Publication Type
Journal Article
Year of Publication
1987
Journal
Journal of the American Chemical Society
Volume
109
Pagination
894–896
ISSN
0002-7863
Abstract
The polymer [104584-99-8] which is synthesized by ring opening olefin-metathesis polymn. of 3,4-diisopropylidenecyclobutene, is sol., transparent, and forms conductive materials (up to 200 $Ømega$-1cm-1) when doped with iodine. The characterization of the material by CP-MAS 13C NMR, ESR, and UV-vis spectroscopy is reported. The electronic structure and the possible mechanisms of conduction are discussed. [on SciFinder(R)]