MIT

Organometallic cross-coupling methods for the synthesis of complex conjugated polymers.

Title

Organometallic cross-coupling methods for the synthesis of complex conjugated polymers.

Publication Type
Journal Article
Year of Publication
1995
Journal
Polymeric Materials Science and Engineering
Volume
73
Pagination
513–514
ISSN
0743-0515
Abstract
The synthesis of conjugated polymers incorporating recognition elements for ions and electron deficient org. mols., e.g., polythiophenes, polyphenylenes, etc., are described. Palladium [Pd(PPh3)4] catalyzed coupling of polythiophenes which form a self-assembled pseudopolyrotaxane and synthesis of conjugated polymers with enhanced chemosensory response are described. The use of these methods for the construction of all carbon ladder polymers, i.e., graphite ribbons is outlined. [on SciFinder(R)]