Title | Aromaticity in Tropone-Containing Polythiophene |
Publication Type | Journal Article |
Year of Publication | 2006 |
Authors | Sugiyasu, K, Song, C, Swager, TM |
Journal | Macromolecules |
Volume | 39 |
Pagination | 5598–5600 |
Date Published | aug |
ISSN | 0024-9297 |
Keywords | tropone contg polythiophene electrochem polymn crystal structure cond |
Abstract | Tropone-Contg. thiophene monomers were prepd. and electrochem. polymd. under ambient conditions to form polymers. The polymers with various concns. of TFA were studied by CV, UV-vis-NIR, and cond. In conclusion, the cond. of tropone-contg. polythiophene can be switched reversibly by a protonation/deprotonation process. The cond. switching mechanism of this polymer is alternative to that of conventional proton dopable polymers such as polyaniline. [on SciFinder(R)] |
URL | http://pubs.acs.org/doi/abs/10.1021/ma061423%2B |
DOI | 10.1021/ma061423+ |