MIT

Poly(anthrylenebutadiynylene)s: precursor-based synthesis and band-gap tuning.

Title

Poly(anthrylenebutadiynylene)s: precursor-based synthesis and band-gap tuning.

Publication Type
Journal Article
Year of Publication
2007
Journal
Angewandte Chemie, International Edition
Volume
46
Pagination
8480–3
Date Published
jan
ISSN
1433-7851
Abstract
Skipping the monomer: A highly efficient reductive aromatization reaction transforms an unconjugated precursor polymer into a high-mol.-wt., butadiyne-linked anthracene homopolymer. Photophys. and electrochem. analyses reveal that some of these new materials display remarkable stability in both neutral and doped states and have unusually low intrinsic band gaps. [on SciFinder(R)]