MIT

Synthesis of regioregular poly(methylpyridinium vinylene). An isoelectronic analog to poly(phenylenevinylene).

Title

Synthesis of regioregular poly(methylpyridinium vinylene). An isoelectronic analog to poly(phenylenevinylene).

Publication Type
Journal Article
Year of Publication
1995
Journal
Advanced Materials (Weinheim, Germany)
Volume
7
Pagination
145–147
ISSN
0935-9648
Abstract
The prepn. of head-to-head (I), head-to-tail (II), and random (III) regioisomeric forms of the title compd. is described. Electrochem. data from cyclic voltammograms are reported. Methylation to give the quaternary regioisomers resulted in a decrease in cond. for the reduced forms of I and III isomers (to <10-7 S/cm). The quaternary II isomer had a cond. of ~{}2.5 x 10-5 S/cm. [on SciFinder(R)]