Synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl radical.

Title

Synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl radical.

Publication Type

Journal Article

Year of Publication

2010

Authors

Journal

The Journal of organic chemistry

Volume

Pagination

3533–6

Date Published

may

ISSN

1520-6904

Keywords

Allyl Compounds, Allyl Compounds: chemical synthesis, Allyl Compounds: chemistry, Crystallography, Free Radicals, Free Radicals: chemical synthesis, Free Radicals: chemistry, Models, Molecular, Molecular Structure, Solubility, Water, Water: chemistry, X-Ray

Abstract

The design and synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl (BDPA) radical via the conjugate addition of a derivatized fluorene nucelophile is described. The compound is designed for use in dynamic nuclear polarization NMR. Its 9 GHz EPR spectrum in glycerol/water is reported.

URL

http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=2882179&tool=pmcentrez&rendertype=abstract

DOI

http://dx.doi.org/10.1021/jo100577g

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