MIT

Chiral Supramolecular Materials from Columnar Liquid Crystals

Title

Chiral Supramolecular Materials from Columnar Liquid Crystals

Publication Type
Journal Article
Year of Publication
2004
Journal
Molecular Crystals and Liquid Crystals
Volume
410
Pagination
247–253
Date Published
jan
ISSN
1542-1406
Abstract
Several $\beta$-diketonate ligands were synthesized which have a chiral directing element and/or a polymerizable moiety. Octahedral iron complexes of these ligands were crosslinked in the columnar hexagonal phase using acyclic diene metathesis (ADMET) polymn. The resulting liq. crystal materials were chiral and retained the order of the mesophase. [on SciFinder(R)]