Title | Fluorous biphase synthesis of a poly(p-phenyleneethynylene) and its fluorescent aqueous fluorous-phase emulsion. |
Publication Type | Journal Article |
Year of Publication | 2010 |
Authors | Lim, J, Swager, TM |
Journal | Angewandte Chemie, International Edition |
Volume | 49 |
Pagination | 7486–8 |
Date Published | oct |
ISSN | 1521-3773 |
Keywords | fluorous biphase polyphenyleneethynylene fluoresce |
Abstract | It's just a phase: A highly fluorinated compd. with a rigid three-dimensional architecture was synthesized as a monomer for poly(p-phenyleneethynylene)s (PPEs). Fluorous biphase reactions were applied for the synthesis of a PPE that is sol. only in fluorous solvents. A fluorous soln. of the polymer could be processed into aq. emulsions that display high fluorescence quantum yields. [on SciFinder(R)] |
URL | http://www.ncbi.nlm.nih.gov/pubmed/20814998 |
DOI | 10.1002/anie.201003111 |