Highly Emissive Iptycene−Fluorene Conjugated Copolymers: Synthesis and Photophysical Properties

TitleHighly Emissive Iptycene−Fluorene Conjugated Copolymers: Synthesis and Photophysical Properties
Publication TypeJournal Article
Year of Publication2008
AuthorsChen, Z, Bouffard, J, Kooi, SE, Swager, TM
JournalMacromolecules
Volume41
Pagination6672–6676
Date Publishedsep
ISSN0024-9297
Keywordsfluorescence solid state excimer iptycene fluorene
Abstract

Iptycene-type quinoxaline and thienopyrazine monomers were successfully synthesized via a condensation between 10-dihydro-9,10-ethanoanthracene-11,12-dione and the corresponding diamines. Copolymers based on fluorene and three iptycene monomers were prepd. via Suzuki coupling reaction, and they exhibited good soly. in appropriate org. solvents. These copolymers are fluorescent in both soln. and the solid state, emitting blue, greenish-blue, and red color due to the different electronic properties of the iptycene comonomers. The difference in their absorption and emission spectra was attributed to the donor-acceptor charge transfer interactions and/or polymer backbone conformational changes induced by steric effects. Moreover, the spectroscopic data clearly demonstrated the insulating effect of iptycene units, which prevented the aggregation of the polymer chains and the formation of excimers in the solid state. [on SciFinder(R)]

URLhttp://pubs.acs.org/doi/abs/10.1021/ma800486a
DOI10.1021/ma800486a