Title | Synthesis of a Novel Poly(iptycene) Ladder Polymer |
Publication Type | Journal Article |
Year of Publication | 2006 |
Authors | Chen, Z, Amara, JP, Thomas, SW, Swager, TM |
Journal | Macromolecules |
Volume | 39 |
Pagination | 3202–3209 |
Date Published | may |
ISSN | 0024-9297 |
Keywords | hyperbaric Diels Alder self polymn ladder polyiptycene synthesis dehydration |
Abstract | A self-polymerizable AB-type monomer for Diels-Alder (D-A) polymn. was prepd., and its polymn. was carried out in the melt phase and at high pressure in soln. The former method generated only low-mol.-wt. polymer, but the latter one offered an efficient polymn. with increased mol. wt., due to the effect of high pressure on reactions with a neg. activation vol. A pyridinium p-toluenesulfonate-catalyzed dehydration reaction of the D-A polymer led to a novel arom. ladder polymer, poly(iptycene), which is sol. in common org. solvents and stable up to 350 °C. The NMR and UV-vis spectra of these polymers match the spectra of their corresponding model compds., the synthesis of which is also reported. [on SciFinder(R)] |
URL | http://pubs.acs.org/doi/abs/10.1021/ma052451f |
DOI | 10.1021/ma052451f |