Title | Fluorescent Conjugated Polymers That Incorporate Substituted 2,1,3-Benzooxadiazole and 2,1,3-Benzothiadiazole Units |
Publication Type | Journal Article |
Year of Publication | 2008 |
Authors | Bouffard, J, Swager, TM |
Journal | Macromolecules |
Volume | 41 |
Pagination | 5559–5562 |
Date Published | aug |
ISSN | 0024-9297 |
Keywords | benzooxadiazole benzothiadiazole fluorescent conju |
Abstract | Heterocyclic monomers based on 2,1,3-benzooxadiazole and 2,1,3-benzothiadiazole bearing solubilizing side chains have been synthesized in high yields over three steps from readily available starting materials. The monomers are efficiently cross-coupled with diynes and bis(boronates) to afford high mol. wt. luminescent poly(arylene ethynylene)s and polyfluorenes that exhibit red-shifted absorption and emission maxima, greater soly., and reduced aggregation. [on SciFinder(R)] |
URL | http://pubs.acs.org/doi/abs/10.1021/ma8010679 |
DOI | 10.1021/ma8010679 |