Title | Near-infrared fluorophores containing benzo[c]heterocycle subunits. |
Publication Type | Journal Article |
Year of Publication | 2008 |
Authors | Meek, ST, Nesterov, EE, Swager, TM |
Journal | Organic letters |
Volume | 10 |
Pagination | 2991–3 |
Date Published | jul |
ISSN | 1523-7060 |
Keywords | Benzene Derivatives, Benzene Derivatives: chemical synthesis, Benzene Derivatives: chemistry, Fluorescent Dyes, Fluorescent Dyes: chemical synthesis, Fluorescent Dyes: chemistry, Heterocyclic Compounds, Heterocyclic Compounds: chemical synthesis, Heterocyclic Compounds: chemistry, Molecular Structure, Near-Infrared, Spectroscopy |
Abstract | The syntheses and spectroscopic properties of eight new push-pull-type near-infrared fluorophores that contain either isobenzofuran or isothianaphthene subunits are presented. The isobenzofuran dyes demonstrate significantly red-shifted absorption compared with their isothianaphthene counterparts, which is attributed to isobenzofuran's more potent pro-quinoidal character. |
URL | http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=2745113&tool=pmcentrez&rendertype=abstract |
DOI | 10.1021/ol800988w |