Title | Synthesis of a BDPA-TEMPO biradical. |
Publication Type | Journal Article |
Year of Publication | 2009 |
Authors | Dane, EL, Maly, T, Debelouchina, GT, Griffin, RG, Swager, TM |
Journal | Organic letters |
Volume | 11 |
Pagination | 1871–4 |
Date Published | may |
ISSN | 1523-7052 |
Keywords | Allyl Compounds, Allyl Compounds: chemical synthesis, Allyl Compounds: chemistry, Crystallography, Cyclic N-Oxides, Cyclic N-Oxides: chemical synthesis, Cyclic N-Oxides: chemistry, Electron Spin Resonance Spectroscopy, Models, Molecular, Molecular Conformation, Molecular Structure, X-Ray |
Abstract | The synthesis and characterization of a biradical containing a 1,3-bisdiphenylene-2-phenylallyl (BDPA) free radical covalently attached to a 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) free radical are described. The synthesis of the biradical is a step toward improved polarizing agents for dynamic nuclear polarization (DNP). |
URL | http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=2714282&tool=pmcentrez&rendertype=abstract |
DOI | 10.1021/ol9001575 |